H_fre_en_2-00li-ion_batteries_poa_80_,_poa_84,_pra_84,_pra_84_g,_psa_81,_psa_82

Safety data sheet
according to 1907/2006/EC, Article 31 / ISO 11014
Printing date 11.12.2012
Version number 2
Revision: 11.12.2012
1 Identification of the substance/mixture and of the company/undertaking
· Product identifier
· Trade name: Li-Ion Batteries POA 80 , POA 84, PRA 84, PRA 84 G, PSA 81, PSA 82
· Relevant identified uses of the substance or mixture and uses advised against
· Article category AC3 Electrical batteries and accumulators
· Application of the substance / the preparation Rechargeable Lithium Ion battery
· Details of the supplier of the safety data sheet
· Manufacturer/Supplier:
Hilti France S.A.
Rond Point Mérantais1, rue Jean Mermoz78778 Magny-les-HameauxTel +33 1 3012 5000Fax +33 1 3012 5012 Customer Service:Tel : 0825 01 05 05 (0.15€/min)Fax : 0825 02 55 55 (0.15€/min)Email : [email protected] · Informing department:
· Emergency telephone number:
Schweizerisches Toxikologisches Informationszentrum - 24 h ServiceTel.: 0041 / 44 251 51 51 (international). Centre Anti-Poisons Permanence médicale téléphonique :Paris: 01 40 05 48 48 Lyon: 04 72 11 69 11Marseille: 04 91 75 25 25 Lille: 0 825 812 822Nancy: 03 83 32 36 36 Angers: 02 41 48 21 21http://www.centres-antipoison.net 2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008
In accordance with article 3 (3) of REACH, this / these item(s) are products.
A product is not subject to the mandatory marking regulations applicable to dangerous substances.
The product is not classified as hazardous to health or environment according to the CLP regulation.
· Label elements
· Labelling according to Regulation (EC) No 1272/2008 Void
· Hazard pictograms Void
· Signal word Void
· Hazard statements Void
· Other hazards
For the battery chemical materials are stored in a hermetically sealed metal case, designed to withstand temperatures and pressures encounteredduring normal use. As a result, during normal use there is no physical danger of ignition or explosion and chemical danger of hazardousmaterials leakage.
It may cause heat generation or electrolite leakage if battery terminals contact with other metals. Elektrolyte is flammable. In case of electrolyteleakage move the battery from fire immediately.
However if exposed to a fire, added mechanical shocks, decomposed, added electric stress by miss-use, the gas release vent will be operated. Thebattery case will be breaked at the extreme, hazardous materials may be released.
Moreover, if heated strongly by a surrounding fire, acrid gas may be emitted.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition/information on ingredients
· Chemical characterization: Mixtures
· Description:
Lithium Ion rechercheable battery pack:Name/type no. of cells energy capacity [Wh]POA 80 2 19,8POA 84 4 55PRA 84 4 33,0PRA 84 G 4 44,0PSA 81 4 37PSA 82 4 36 Safety data sheet
according to 1907/2006/EC, Article 31 / ISO 11014
Printing date 11.12.2012
Version number 2
Revision: 11.12.2012
Trade name: Li-Ion Batteries POA 80 , POA 84, PRA 84, PRA 84 G, PSA 81, PSA 82
· Dangerous components:
This product contains a positive electrode (Lithium cobalt oxide), a negative electrode (graphite) and electrolyte (ethylene carbonate, diethylcarbonate and lithium hexafluorophosphate). The physical form of the product, however, precludes exposure to workers under normalconditions of use.
4 First aid measures
· Description of first aid measures
· General information
This product contains an organic electrolyte. If the electrolyte is leaking out of the battery pack, the following measures have to be taken.
· After inhalation
Take affected persons into the open air and position comfortablySupply fresh air or oxygen; call for doctor.
In case of unconsciousness bring patient into stable side position for transport.
· After skin contact Instantly wash with water and soap and rinse thoroughly. If skin irritation persist, call a physician.
· After eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
· After swallowing Seek immediate medical advice.
· Information for doctor
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed No further relevant information available.
5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet.
Foam · For safety reasons unsuitable extinguishing agents Water with full jet.
· Special hazards arising from the substance or mixture Formation of toxic gases is possible during heating or in case of fire.
· Advice for firefighters
· Protective equipment:
In the event of fire, wear self contained breathing apparatusWear full protective suit.
Use personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition.
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sourcesUse personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition.
Keep people at a distance and stay on the windward side.
· Environmental precautions: Do not allow to enter the ground/soil.
· Methods and material for containment and cleaning up:
Absorb liquid components with liquid-binding material.
Collect mechanically.
· Reference to other sections
See Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.
See Section 13 for information on disposal.
7 Handling and storage
· Handling
· Precautions for safe handling
Do not soak in water or seawater.
Do not expose to strong oxidizers.
Do not give a strong mechanical shock or fling.
Never disassemble, modify or deform.
Do not connect the positive terminal to the negative terminal with electrically conductive material.
Use only the chargers / electric tools specified by Hilti to charge or discharge the battery.
No special precautions necessary if used correctly.
· Information about protection against explosions and fires:
Do not throw into fire or expose to high temperatures (>85°C).
Do not connect the positive terminal to the negative terminal with electrically conductive material.
· Conditions for safe storage, including any incompatibilities
· Storage
· Requirements to be met by storerooms and containers:
Avoid direct sunlight, high temperature, high humidity.
Store in a cool place (temperature: -20°C ~ 35°C, humidity: 45 - 85%) Safety data sheet
according to 1907/2006/EC, Article 31 / ISO 11014
Printing date 11.12.2012
Version number 2
Revision: 11.12.2012
Trade name: Li-Ion Batteries POA 80 , POA 84, PRA 84, PRA 84 G, PSA 81, PSA 82
· Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials.
Store away from water.
Do not store together with electrically conductive materials.
· Further information about storage conditions:
The accu-pack should be stored at 30 to 50% of the charging capacity.
Avoid storing in places where it is exposed to static electricity.
Protect from heat and direct sunlight.
· Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
· Additional information about design of technical systems: No further data; see item 7.
· Control parameters
· Components with limit values that require monitoring at the workplace:
No technical measures are necessary during normal use. In case of leakage of substances contained within the cell, the information below maybe useful.
· Additional information: The lists that were valid during the compilation were used as basis.
· Exposure controls
· Personal protective equipment
· General protective and hygienic measures The usual precautionary measures should be adhered to general rules for handling chemicals.
· Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing apparatus that isindependent of circulating air.
· Protection of hands:
Protective glovesEN 374The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
· Material of gloves Nitrile rubber, NBR
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
· Eye protection: Tightly sealed safety glasses.
· Body protection: Protective work clothing.
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
· Odour:
· Odour threshold:
· pH-value:
· Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
· Flash point:
· Inflammability (solid, gaseous)
· Ignition temperature:
· Decomposition temperature:
· Self-inflammability:
· Danger of explosion:
Risk of explosion by shock, friction, fire or other sources of ignition.
· Critical values for explosion:
· Vapour pressure:
· Density
· Relative density
· Vapour density
· Evaporation rate
· Solubility in / Miscibility with
· Partition coefficient (n-octanol/water): Not applicable
· Viscosity:
dynamic:
Safety data sheet
according to 1907/2006/EC, Article 31 / ISO 11014
Printing date 11.12.2012
Version number 2
Revision: 11.12.2012
Trade name: Li-Ion Batteries POA 80 , POA 84, PRA 84, PRA 84 G, PSA 81, PSA 82
kinematic:
· Solvent content:
Organic solvents:
· Other information
No further relevant information available.
10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known
· Conditions to avoid No further relevant information available.
· Incompatible materials: Conductive materials, water, seawater, strong oxidizers and strong acids.
· Hazardous decomposition products: Acrid or harmful gas is emitted during fire
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect:
· on the skin:
This product contains an organic electrolyte. If the electrolyte is leaking out of the battery pack, the following effects are known when gettinginto contact:Irritant to skin and mucous membranes.
· on the eye: Irritant effect.
· Sensitization: No sensitizing effect known.
12 Ecological information
· Toxicity
· Aquatic toxicity: No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Additional ecological information:
· General notes:
Do not allow battery packs to penetrate the soil.
The battery cell may corrode and electrolyte may leak.
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation Dispose of this battery pack according to national regulations or return the used battery pack to Hilti.
· European waste catalogue
16 00 00 WASTES NOT OTHERWISE SPECIFIED IN THE LIST 16 06 05 other batteries and accumulators 20 00 00 MUNICIPAL WASTES (HOUSEHOLD WASTE AND SIMILAR COMMERCIAL, INDUSTRIAL AND INSTITUTIONAL WASTES) INCLUDING SEPARATELY COLLECTED FRACTIONS 20 01 00 separately collected fractions (except 15 01) 20 01 34 batteries and accumulators other than those mentioned in 20 01 33 · Uncleaned packagings:
· Recommendation:
Disposal must be made according to official regulations.
Dispose of packaging according to regulations on the disposal of packagings.
14 Transport information
· UN-Number
· ADR, ADN, IMDG, IATA
Safety data sheet
according to 1907/2006/EC, Article 31 / ISO 11014
Printing date 11.12.2012
Version number 2
Revision: 11.12.2012
Trade name: Li-Ion Batteries POA 80 , POA 84, PRA 84, PRA 84 G, PSA 81, PSA 82
· UN proper shipping name
· ADR
· ADN, IMDG, IATA
· Transport hazard class(es)
· ADR, ADN, IMDG, IATA
· Class
· Packing group
· ADR, IMDG, IATA
· Environmental hazards:
· Marine pollutant:
· Special precautions for user
· Transport in bulk according to Annex II of MARPOL73/78 and
the IBC Code
· Transport/Additional information:
Not dangerous according to the above specifications.
Lithium-ion batteries are tested in accordance with: UN manual of Testsand Criteria, Part III, subsection 38.3 · ADR
· Remarks:
Lithium ion batteries offered for carriage are not subject to otherprovisions of ADR/RID/GGVS/E.
They meet the requirements of special provision SP 188.
· IMDG
· Remarks:
Lithium ion batteries offered for carriage are not subject to otherprovisions of IMDG/GGVSee.
They meet the requirements of special provision SP 188.
· IATA
· Remarks:
Lithium ion batteries offered for transport are not subject to otheradditional requirements of these regulations.
They meet the requirements of Packing Instruction 965/II (<2 batteries)and 965/IB (>2 batteries).
· UN "Model Regulation":
15 Regulatory information
· Safety, health and environmental regulations/legislation specific for the substance or mixture
· National regulations
- Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,Evaluation, Authorisation and Restriction of Chemicals (REACH)- Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003 on the restriction of the use of certain hazardoussubstances in electrical and electronic equipment- Directive 2002/96/EC of the European Parliament and of the Council of 27 January 2003 on waste electrical and electronic equipment(WEEE)- Directive 2006/66/EC of the European Parliament and of the Council of 6 September 2006 on batteries and accumulators and waste batteriesand accumulators and repealing Directive 91/157/EEC · Other regulations, limitations and prohibitive regulations None
· Substances of very high concern (SVHC) according to REACH, Article 57 None
· Chemical safety assessment: not required.
16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall notestablish a legally valid contractual relationship.
· Department issuing data specification sheet:
Hilti Entwicklungsgesellschaft mbHHiltistrasse 6D-86916 KauferingTel.: +49 8191 906310Fax: +49 8191 90176310e-mail: [email protected] · Contact: Mechthild Krauter
· Abbreviations and acronyms:
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail)ICAO: International Civil Aviation OrganizationADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationGHS: Globally Harmonized System of Classification and Labelling of Chemicals · * Data compared to the previous version altered.

Source: https://www.hilti.fr/medias/sys_master/documents/h61/9082994982942/IBD_WWI-00000000000000016562_000_APC_RAW.pdf